Methoxy(cyclooctadiene)rhodium(I) dimer

98%, Rh>42%

Reagent Code: #209812
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CAS Number 12148-72-0

blur_circular Chemical Specifications

scatter_plot Molecular Information
Weight 476.18 g/mol
Formula C₁₈H₂₂O₂Rh₂
badge Registry Numbers
MDL Number MFCD08457639
thermostat Physical Properties
Boiling Point 153.5°C at 760 mmHg
inventory_2 Storage & Handling
Storage 2-8°C, sealed, dry

description Product Description

Widely used as a homogeneous catalyst in organic synthesis, particularly in rhodium-catalyzed addition reactions such as hydroformylation, hydrosilylation, and conjugate additions. It serves as a precursor to active rhodium catalysts due to the labile cyclooctadiene and methoxy ligands, which readily dissociate to allow substrate coordination. Commonly employed in asymmetric synthesis when paired with chiral ligands, enabling the formation of enantiomerically enriched products. Its solubility in organic solvents makes it suitable for use in solution-phase reactions under mild conditions. Also utilized in C–H activation and cross-coupling transformations in pharmaceutical and fine chemical manufacturing.

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Size Availability Unit Price Quantity
inventory 100 mg
10-20 days ฿6,610.00
inventory 250 mg
10-20 days ฿14,830.00

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