(5R)-6,6'-bis(di-p-tolylphosphaneyl)-2,2',3,3'-tetrahydro-5,5'-bibenzo[b][1,4]dioxine
97%
Reagent
Code: #231855
CAS Number
1306747-78-3
blur_circular Chemical Specifications
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Molecular Information
Weight
694.73 g/mol
Formula
C₄₄H₄₀O₄P₂
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Registry Numbers
MDL Number
MFCD34598597
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Storage & Handling
Storage
Room temperature, seal, dry, inert gas
description Product Description
Used as a chiral bidentate phosphine ligand in asymmetric catalysis, particularly in transition metal-catalyzed reactions such as hydrogenation, cross-coupling, and C–H activation. Its rigid, C2-symmetric backbone enhances enantioselectivity by providing a well-defined chiral environment around the metal center. Effective in rhodium- and ruthenium-catalyzed asymmetric hydrogenations of prochiral olefins and ketones, leading to high enantiomeric excess. Also employed in palladium-catalyzed transformations where precise stereocontrol is required. The electron-rich diarylphosphine groups improve catalyst stability and activity.
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