(5R)-6,6'-bis(di-p-tolylphosphaneyl)-2,2',3,3'-tetrahydro-5,5'-bibenzo[b][1,4]dioxine

97%

Reagent Code: #231855
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CAS Number 1306747-78-3

blur_circular Chemical Specifications

scatter_plot Molecular Information
Weight 694.73 g/mol
Formula C₄₄H₄₀O₄P₂
badge Registry Numbers
MDL Number MFCD34598597
inventory_2 Storage & Handling
Storage Room temperature, seal, dry, inert gas

description Product Description

Used as a chiral bidentate phosphine ligand in asymmetric catalysis, particularly in transition metal-catalyzed reactions such as hydrogenation, cross-coupling, and C–H activation. Its rigid, C2-symmetric backbone enhances enantioselectivity by providing a well-defined chiral environment around the metal center. Effective in rhodium- and ruthenium-catalyzed asymmetric hydrogenations of prochiral olefins and ketones, leading to high enantiomeric excess. Also employed in palladium-catalyzed transformations where precise stereocontrol is required. The electron-rich diarylphosphine groups improve catalyst stability and activity.

shopping_cart Available Sizes & Pricing

Size Availability Unit Price Quantity
inventory 100mg
10-20 days ฿9,190.00
inventory 250mg
10-20 days ฿15,610.00
inventory 1g
10-20 days ฿51,660.00

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