(2R,2'R,3R,3'R)-3,3'-Di-tert-butyl-2,2'-diethyl-2,2',3,3'-tetrahydro-4,4'-bibenzo[d][1,3]oxaphosphole
≥97%
Reagent
Code: #229320
CAS Number
2634687-61-7
blur_circular Chemical Specifications
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Molecular Information
Weight
442.51 g/mol
Formula
C₂₆H₃₆O₂P₂
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Registry Numbers
MDL Number
MFCD32201256
thermostat
Physical Properties
Boiling Point
560.2±50.0 °C(Predicted)
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Storage & Handling
Storage
2-8°C, Sealed, Inert Gas
description Product Description
Used as a chiral ligand in asymmetric catalysis, particularly in transition metal-catalyzed reactions such as hydrogenation, cross-coupling, and hydroformylation. Its rigid backbone and stereogenic centers enable high enantioselectivity, making it valuable in the synthesis of optically active pharmaceuticals and fine chemicals. The phosphorus center coordinates effectively with metals like rhodium, ruthenium, and palladium, enhancing catalytic activity and stereocontrol. Its steric bulk from tert-butyl and ethyl groups helps prevent unwanted side reactions and stabilizes the active catalyst species.
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