(5R)-6,6'-Bis(bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphaneyl)-2,2',3,3'-tetrahydro-5,5'-bibenzo[b][1,4]dioxine
95%
Reagent
Code: #229231
CAS Number
1862251-64-6
blur_circular Chemical Specifications
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Molecular Information
Weight
1207.58 g/mol
Formula
C₇₆H₁₀₄O₈P₂
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Registry Numbers
MDL Number
MFCD34598631
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Physical Properties
Boiling Point
1005.6±65.0 °C(Predicted)
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Storage & Handling
Storage
Room temperature, seal, inert gas
description Product Description
Used as a chiral bidentate phosphine ligand in asymmetric catalysis, particularly in enantioselective hydrogenation and cross-coupling reactions. Its sterically hindered, electron-rich structure enhances metal complex stability and promotes high enantioselectivity with transition metals like rhodium, ruthenium, and palladium. Commonly employed in the synthesis of fine chemicals, pharmaceuticals, and agrochemicals where precise stereochemical control is critical. The dioxine backbone provides rigidity, improving chiral induction, while the methoxy and tert-butyl groups contribute to solubility and prevent unwanted side reactions.
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