N-[(11bR)-2,6-Di-9-anthracenyl-4-oxido-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoromethanesulfonamide
≥98%,≥99% e.e.
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description Product Description
This highly enantiopure chiral organocatalyst (>99% e.e.), N-[(11bR)-2,6-bis(9-anthracenyl)-4-oxido-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoromethanesulfonamide, features a BINOL-derived phosphorus core with sterically demanding di-9-anthracenyl substituents. It serves as a powerful Brønsted acid for asymmetric catalysis, enabling high enantioselectivity in reactions such as Pictet-Spengler cyclizations, aza-Friedel-Crafts alkylations, enantioselective protonations, and other C-C/C-N bond formations. The triflimide moiety enhances acidity, while the chiral scaffold ensures stereocontrol via steric and π-stacking interactions. Primarily used in pharmaceutical and fine chemical synthesis to produce enantiomerically pure compounds; it is a specialty chemical intermediate/ligand, not a commodity.
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