1,3-Dimesitylimidazolidin-2-ylidene
95%
Reagent
Code: #176162
CAS Number
173035-11-5
blur_circular Chemical Specifications
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Molecular Information
Weight
306.45 g/mol
Formula
C₂₁H₂₆N₂
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Registry Numbers
MDL Number
MFCD11973794
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Physical Properties
Melting Point
85-100 °C
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Storage & Handling
Storage
2-8°C
description Product Description
Used as a highly sterically hindered N-heterocyclic carbene (NHC) ligand in organometallic catalysis. It stabilizes reactive metal centers in transition metal complexes, particularly in ruthenium-based olefin metathesis catalysts, enhancing their activity and longevity. Its bulky mesityl groups provide strong electron donation and prevent catalyst decomposition, making it valuable in ring-closing metathesis and polymerization reactions. Also employed in palladium-catalyzed cross-coupling reactions to improve catalyst stability under harsh conditions. Additionally, serves as a ligand in CO2 activation and small molecule fixation due to its strong sigma-donating ability.
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