(11bS)-N-(2,6-Di(naphthalen-1-yl)-4-oxido-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)-1,1,1-trifluoromethanesulfonamide
97%
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Used as a chiral ligand in asymmetric catalysis, particularly in transition metal-catalyzed reactions such as asymmetric hydrogenation and cross-coupling reactions. Its rigid, sterically hindered structure enables high enantioselectivity in the synthesis of chiral molecules, making it valuable in pharmaceutical and fine chemical industries for producing single-enantiomer compounds. The phosphorus center coordinates with metals like rhodium, ruthenium, or palladium, forming catalytically active complexes. Its naphthyl groups enhance π-stacking interactions and steric control, improving selectivity in complex transformations. It exhibits a certain degree of stability towards air and moisture, facilitating easy handling in typical reaction conditions.
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