(11bR)-N-(2,6-bis(4-nitrophenyl)-4-oxido-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)-1,1,1-trifluoromethanesulfonamide
97%
Reagent
Code: #229253
CAS Number
2758008-05-6
blur_circular Chemical Specifications
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Molecular Information
Weight
729.61 g/mol
Formula
C₃₃H₂₇F₃N₃O₉PS
thermostat
Physical Properties
Boiling Point
840.3±75.0 °C(Predicted)
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Storage & Handling
Density
1.60±0.1 g/cm3(Predicted)
Storage
Room temperature, light-proof, inert gas
description Product Description
Used as a chiral catalyst ligand in asymmetric synthesis, particularly in enantioselective transformations such as hydrogenation and cross-coupling reactions. Its rigid dinaphthyl backbone and phosphorus center with defined stereochemistry enable high enantioselectivity in the production of pharmaceutical intermediates and fine chemicals. The presence of electron-withdrawing nitro groups enhances ligand stability and influences metal coordination, improving catalytic efficiency. Commonly employed with transition metals like palladium, rhodium, or iridium in homogeneous catalysis.
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