(11bS,11′bS)-4,4′-(9,9-DiMethyl-9H-xanthene-4,5-diyl)bis-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin

solid

Reagent Code: #36169
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CAS Number 349114-57-4

blur_circular Chemical Specifications

scatter_plot Molecular Information
Weight 838.8200000000001 g/mol
Formula C₅₅H₃₆O₅P₂
badge Registry Numbers
MDL Number MFCD09842740
thermostat Physical Properties
Melting Point 195-207℃ (dec.)
inventory_2 Storage & Handling
Storage 2-8℃

description Product Description

This compound is a chiral bis(dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin) ligand based on a 9,9-dimethylxanthene backbone connected to two dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin units with (11bS,11′bS) configuration. It is primarily utilized as a ligand in asymmetric catalysis, enabling high enantioselectivity in metal-catalyzed reactions such as hydrogenations, cross-couplings (e.g., Suzuki-Miyaura, Heck), and allylic substitutions. The rigid xanthene core and bulky binaphthyl-derived phosphorus moieties provide excellent steric control and stability to metal complexes, particularly with palladium, rhodium, and ruthenium, making it suitable for the synthesis of enantiopure pharmaceuticals, agrochemicals, and fine chemicals. Its chiral nature ensures stereoselective outcomes in reactions requiring precise control over molecular asymmetry.

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Size Availability Unit Price Quantity
inventory 100mg
10-20 days ฿8,090.00

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